I already have:
Dune
Foundation
Leviathan wakes
Neuromancer
- Blindsight by Peter Watts 
- Children of Time trilogy by Adrian Tchaikovsky 
"Three worlds collide" by Eliezer Yudkowsky. First contact with aliens, moral relativism, game theory, and a hilarious cameo by prediction markets. Available here.
More recent suggestions:
- The Three-Body Problem": A secret military project in China makes contact with an alien civilization, leading to unforeseen consequences and a global scientific investigation. 
- "The Dark Forest": Facing the threat of an alien invasion, humanity scrambles to understand the universe's cosmic principles and develop strategies for survival. 
- "Death's End": Set in a distant future, the final book explores humanity's place in the universe, advanced technologies, and multi-dimensional challenges. 
Looking at your list I can suggest a few more:
- "Snow Crash" by Neal Stephenson - An influential cyberpunk novel with a unique take on virtual reality.
- "Hyperion" by Dan Simmons - A sprawling space epic with fantastic world-building and multiple perspectives.
- "Do Androids Dream of Electric Sheep?" by Philip K. Dick - The book that inspired the movie Blade Runner, exploring themes of artificial intelligence.
- "The Left Hand of Darkness" by Ursula K. Le Guin - A thought-provoking novel that explores gender and society on an alien planet.